Not necessarily; boxing is an aspect of mixed-martial arts. That's why it's called MMA. So if you looked at Calzaghe as an MM-artists, well, obviously his punching far exceeds Bisping-ping. But overall, they are two different sports, and as long as Bisping knows he can't stand with Calzaghe, he would likely win.
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It's like asking who would win in a triathlon, Lance Armstrong or the world's 10th best triathlete. Clearly the triathlete wins, because cycling isn't the whole game.
Bisping takes JC down almost immediately for some vicious GnP. Obviously, a boxing match would bring a similar result in Calzaghe's favor.