Hell no. Paulie can hype a fight with the best of them but even he would have a tough time selling this matchup to the casual fan.
If Paulie wins the rumored Shawn Porter fight at the end of this year, then beats Broner in a rematch to win his WBA title back, then unifies with another top WW at the end of next year... a fight with Floyd becomes acceptable. This timeline would put it at somewhere around May 2015. As for Floyd KO's, he's got 3 in his 11 fights at WW+. Not bad for a JLW having moved up. He fights guys who never get KO'd. Just look at the combined KO defeats of the 8 fighters since his move up to WW that he didn't KO.
Paulie would be a great fight for Danny Garcia's Welterweight debut. I could see them selling it as a NY vs. Philly; Italian vs. Puerto Rican thing. Fight could have some legs on the East Coast (Barclay's Center; Wells Fargo Arena).